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Exodus 7:4

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4 But Pharaoh shall not hearken to you, that I may lay my hand upon Egypt, and bring forth my armies, my people the children of Israel, out of the land of Egypt, by great judgments.

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Exodus 7:20

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20 And Moses and Aaron did so, as the LORD commanded; and he lifted up the rod and smote the waters that were in the river, in the sight of Pharaoh, and in the sight of his servants; and all the waters that were in the river were turned into blood.