Genesis 4:5

⁵ ἐπὶ δὲ καιν καὶ ἐπὶ ταῖς θυσίαις αὐτοῦ οὐ προσέσχεν καὶ ἐλύπησεν τὸν καιν λίαν καὶ συνέπεσεν τῷ προσώπῳ